Book/Report

FZJ-2017-04055

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png The Photolysis of Ammonia at 2062 $\mathring{A}$ in the Presence of Propane

Groth, W. E. ; Schurath, U. ; Schindler, R. N.

1968
Kernforschungsanlage Jülich, Verlag Jülich

Please use a persistent id in citations: http://hdl.handle.net/2128/14652

Report No.: Juel-0523-PC

Abstract: Amnonia was photolyzed at 2o62 $\mathring{A}$ in the presence of propane as a hydrogen atom scavenger. The only photo process at this wavelength is shown to be $(a) NH_{3} + hv (2062\mathring{A}) \longrightarrow NH_{2} (^{2}B_{1}) + H$. // $H_{2}, N_{2}, N_{2}H_{4}, C_{3}H_{6}, C_{6}H_{14}, i-C_{3}H_{7}NH_{2}, n-C_{3}H_{7}NH_{2}$ and small amounts of unidentified arnines were produced in the photolyses. All products were determined quantitatively as functions of absorbed irradiation dose. A reaction mechanism is developped on the basis of the observed quanturn yields. The ratio of disproportionation to addition reactions between amino and propyl radicals is obtained to be 0.21 $\pm$ 0.07.

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Contributing Institute(s):

1. Publikationen vor 2000 (PRE-2000)

Research Program(s):

1. 899 - ohne Topic (POF3-899) (POF3-899)

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Database coverage:

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